聚酯樹脂粉末塗料msds

㈠ 求純聚酯粉末塗料的MSDS

**粉末塗料
安全數據表
粉末塗料
產品及參考：所有提供 *****資料的產品

發布日期：2009年**月*日
1 產品和公司地址
產品名稱 熱固性粉末塗料
應用 靜電噴塗
公司地址 安徽省黃山市
緊急情況聯系電話 ****
2.成分構成/信息
在1997化學品（危險品知識與包裝）規章的范圍內體現健康危害的物質:
名稱 含量范圍 代表符號 R-術語（*）
異氰尿酸三縮水 0.1至<5.0% T R46 R23/25 R48/22
甘油酯(TGIC) R41 R43
（*）詳見16小節
3．危害識別
該產品因含有TGIC被定為具有毒性。可能會有損害遺傳基因的風險。可能引起皮膚接觸性過敏。吸入和誤食均有傷害。
4．急救措施
一般：
若有任何疑問或有症狀持續出現，請尋醫助。
保證失去意識的患者口中無任何東西。
吸入：
移到通風處，保持患者體溫和靜止。如果患者呼吸不規律或停止，進行人工呼吸急救。保證口中無異物。如果失去意識，安置在恰當位置並尋醫助。
眼睛接觸：
取下隱形眼睛。用大量干凈的清水沖洗至少十分鍾，保證眼皮張開並尋醫助。
皮膚接觸：
脫下被污染的衣物。用肥皂和水或者是合適的皮膚清潔劑徹底清洗。切忌使用溶劑或稀釋劑。
吞服：
如不慎吞食，立即尋求醫助。保持患者靜躺，切勿導吐。
5．消防措施
滅火媒介：
建議：水，泡末，乾粉，CO2，水噴淋或水霧
禁止使用：高壓惰性氣體（如CO2），水槍噴射
建議：
火災現場濃厚的黑煙包含很多由於燃燒產生的有害物質（參看第10小節）。暴露於這種分解的物質中對健康有害。需要自帶呼吸器的器械。用水噴的方式冷卻暴露在火中的密閉容器。切勿把滅火器的流出物直接排到下水道或河道中。
6．應急意外泄露

排除火源，保證場地通風。無關人員遠離現場。避免吸入灰塵。涉及到的保護措施列在7、8小節。打掃溢出粉末應使用防靜電的真空清潔器或濕的清潔刷，並根據廢物處理規則（參看13小節）收集在密閉容器中待處理。切勿使用掃把，以免形成灰塵層和靜電積累。請勿直接排放到下水道或河道中。
如果產品進入下水道或河道，應立即聯系當地自來水公司；如果污染了河流、小溪或湖泊，應求助當地環保部門。
7．處置和存儲
處置
採取措施以預防灰塵積聚到高於爆炸或偶然爆炸極限。
電氣和照明設備應根據相宜標准進行保護，切勿讓灰塵接觸熱表面、火星或其它點火火源。
保證容器密封。排除熱源、火星和明火。避免吸入灰塵。在儲存和使用區域嚴禁抽煙、進食和飲水。
操作人員應佩帶防靜電鞋，地面保持導電。
涉及到個人防護參看8小節。
本產品包裝物應交有資質的部門處理。
儲存
閱讀儲存措施標識。一般貯存在35℃之下、通風良好、乾燥的室內，不得靠近火源、暖氣，避免陽光直射。禁止抽煙。不經授權不得進入。打開的包裝一定要重新密封，並擺放適當位置防止泄露。
8．暴露控制/個人防護
暴露極限
物質 職業暴露極限
8小時 TWA（1） 15分鍾 STEL（2）
mg/m3 (3) mg/m3 (3)
TGIC 0.1MEL
注釋：
（1） 長期暴露極限—8小時時間的加權平均值
（2） 短期暴露極限—15分鍾參考周期
（3） 「OES」是指Occupational Exposure Standard(職業暴露標准)， 「MEL」是指Maximum Exposure Limit(最大暴露極限)， 「OELS」是取自於EH40的當前版本。
對TGIC的暴露可以用MDHS85（HSE）方法來測量。對TGIC的暴露還可以通過另外一種方法來測量，即測出總吸入微粒（TIP）然後再計算出這種物質中TGIC的含量是多少。
對於TGIC含量在0.1%—5.0%范圍的產品，TIP的暴露低於2 mg/m3 就意味著TGIC的暴露低於0.1 mg/m3 MEL。

具有呼吸道疾病和過敏反應病史的人員必須要在適當的醫療監督下才能暴露於此產品中或處理此類產品。
技術措施
避免吸入粉塵。使用現場的排氣通風和抽風裝置來減少粉塵。如果這些措施仍不能將粉塵濃度控制在職業暴露極限之下，就需要佩帶合適的呼吸保護裝備。（參考下面的「個人防護」章節）
個人防護
用來控制對有害物質的暴露所有的PPE（個人防護裝備）包括RPE（呼吸保護裝備）都必須達標。
呼吸保護：
如果噴塗人員或附近其他人員對於產品的暴露不能控制在職業暴露極限之下，或是技術控制措施沒有合理的改進，本產品噴塗時則必須佩帶合適的呼吸保護裝置。
手的保護：
皮膚暴露可能發生的區域，建議從手套供應商處選擇合適的型號。
眼睛的保護：
當有可能暴露於產品中時，應佩帶相應的防護鏡免於灰塵的暴露。
皮膚的保護：
通常棉或合成棉的用品比較合適。
選擇防護布料時一定要注意，應確保避免脖子和手腕處皮膚與粉末接觸，以免其受刺激發炎。
9．物理和化學性質
物理狀態 細粉狀
比重 1.2—1.9
在水中的溶解性 不溶於水
最低點燃溫度 400℃
最低點燃能量： 5—20mJ
最低爆炸濃度： 20—70g/m3
10．穩定性和反應活性
在建議的貯存和處理條件（見7小節）下產品保持穩定。在燃燒中，產品會分解有害物如煙、CO、CO2，也可能產生其它氮氧化合物。
11． 毒性信息
關於產品本身沒有可獲得的數據。
粉末可能會引起局部皮膚褶皺處或衣物緊裹處刺激。
12．生態信息
關於產品本身沒有可獲得的數據。
該產品含有對水生物有害的TGIC，因此可能會對水生環境造成長期的不利影響。
本產品不準排入河流或下水道，或是在可能影響土壤或地表水的地方沉積。
當應用本產品時應遵循在《環境保護法》中制定的《空氣污染控制》規章要求。
13．處理考慮因素
不允許排入河道或下水道或是在可能影響土壤或地表水的地方沉積。廢棄物包括空的容器，應根據在《污染控製法》和《環境保護法》中制定的規章處理。咨詢你的廢棄物處理商以獲得更詳盡的信息。
14．運輸信息
運輸時確保包裝物的密封、完整，確保運輸人員在發生泄露等事件時知道如何處理。在國際章程項下該產品並未被劃分為危險運輸品。
15．管理信息
根據1997《化學品規章》（有害信息和包裝）的要求該產品的安全術語如下：
該產品含有TGIC被定為有毒級別。
R46 可能損害遺傳基因
R43 可能引起皮膚接觸性過敏
R36 對眼睛有刺激性
R20/22 若吸入或吞服均有損害
S24/25 避免與皮膚和眼睛接觸
S45 意外事件或是你感覺不佳，立即需求醫助（可能的話向醫生出示標簽）
S38 若通風不足應佩帶合適的呼吸器具
S53 避免暴露—使用前熟悉特殊指導說明
此安全數據頁里所包含的信息，根據其它健康和安全法律要求，並不能構成用戶本身工作場地風險的評估。使用本產品時為了工作的健康和安全，應該遵循物質對健康危害的控制章程。
16．其他信息
此安全數據頁里所包含的信息是根據1997《化學品規章》（有害信息和包裝）的要求提供。
在第二小節包含的R術語全文是：
R23/25 若吸入或吞服均有毒性
R41 對眼睛嚴重損傷的風險
R43 可能引起皮膚接觸性過敏
R46 可能損害遺傳基因
R48/22 有害：長期暴露和誤食對健康的嚴重損害危險
在沒有向粉末供應商聯系並獲得書面的作業指導前，本產品不得用作除第一部分所列的其他用途。若本產品是在供應商控制之外其他特殊條件下使用，用戶應確保遵從相關的法律要求。
此安全數據頁里所包含的信息是基於現有的知識形態和當前的國家法律。它對本產品健康、安全和環境方面提供指導，但做特殊用途時並不能提供技術性能或穩定性的保證。
更詳盡的信息和建議可從下列獲得：
《1999物質有害健康控制章程》（SL1999：437）
《英國塗料聯盟粉末塗料靜電噴塗（安全慣例代碼）應用》（01372 360 660）
《1992操作處理規章手冊》（SL 1992：2793）
《化學品的入庫貯存》：密封危險品的貯存 HS（G）71
《1992環境保護章程》（SL 1992：2839）
《1997化學品（危險品信息和包裝）章程》（SL 1997：3247）

**** Powder Coating
SAFETY DATA SHEET NO 29
COATING POWDER
Proct and reference：ALL PRODUCT PROVIDED THE SDS 29 MATERIAL

Date of Issue：***. **st, 2009

1 IDENTIFICATION OF THE PREPARATION AND COMPANY
Proct name and/or code: Thermosetting Coating Powder
Intended use: ***
Name and full address: *****
****

Emergency phone number: ***

2. COMPOSITION/INFORMATION ON INGREDIENTS

Substances presenting a health hazard within the meaning of the Chemicals (Hazard Information and Packaging) Regulations 1997:

Name Conc. Range Symbol Letter R-phrases（*）
Triglycidyl(TGIC) 0.1 to <5.0% T R46, R23/25, R48/22,R41,R43
Isocyanurate

（*）For full text see section 16
3.HAZARDS IDENTIFICATION

This proct contains TGIC and is classified as toxic. Possible risk of heritable genetic damage. May cause sensitisation by skin contact and may be irritating to eyes. Harmful by inhalation and if swallowed.

4. FIRST AID MEASURES

General:
In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.

Inhalation：
Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice.

Eye contact：
Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice.

Skin Contact:
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners.

Ingestion:
If accidentally swallowed, obtain medical attention. Keep at rest. Do NOT ince vomiting.

5. FIRE FIGHTING MEASURES

Extinguishing media:
Recommended: water, extinguisher of foam, Powder and Carbon dioxide, water spray/mist.
Not to be used: high pressure inert gas（e.g. CO2），water jets.

Recommendations:
Fire will proce dense black smoke containing hazardous procts of combustion (see Section 10). Exposure to decomposition procts may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or watercourses.

6. ACCIDENTAL RELEASE MEASURES

Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing st. Refer to protective measures listed in Sections 7&8. Contain and collect spillage with an anti- electrostatic vacuum cleaner or by wet brushing and place in a closed container for disposal in accordance with the waste regulations (see Section 13). Do not use a dry brush or static electricity can be created. Do not allow to enter drains or watercourses.

If the proct enters drains or sewers, the local water company should be contacted immediately; in case of contamination of streams, rivers or lakes, the relevant environment agency.

7. HANDLING AND STORAGE

Handling:
Precautions should be taken to prevent the formation of sts in concentrations above explosive or occupational exposure limits.

Electrical equipment and lighting should be protected to appropriate standards and to prevent st coming into contact with hot surfaces, sparks or other ignition sources.

Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Avoid the inhalation of sts. Smoking, eating and drinking should be prohibited in areas of storage and use.

Operators should wear anti-static footwear and floors should be electrically conctive.

For personnel protection see Section 8.

The containers of this proct should be handled in qualified department.

Storage:
Observe the label precaution. Store below 35℃ in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened should be properly released and upright to prevent leakage.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Exposure Limits:

Substance Occupational Exposure Limits
8hr TWA（1） 15min STEL（2）
mg/m3 (3) mg/m3 (3)

TGIC 0.1 MEL
Notes:
（1） Long term exposure limit—8 hour time weighted average
（2） Short term exposure limit—15 minutes reference period
（3） 「OES」indicates an Occupational Exposure Standard. 『MEL』 indicates a Maximum Exposure Limit. OELS are taken from the current version of EH40.
Exposure to TGIC can be measured by the method described in MDHS 85 (HSE). An estimate of exposure to TGIC can also be carried out by measuring exposure to total inhalation particulate(TIP), and then calculating how much of this material is TGIC.
For procts with TGIC content in the range 0.1 to <5.0% exposure to TIP below 2 mg/m3 will mean exposure to TGIC will be below the MEL of 0.1 mg/m3.

Persons with a history respiratory problems or allergic responses should only be exposed to, or handle, this proct under appropriate medical supervision.

Engineering Measures:
Avoid the inhalation of sts. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If there are not sufficient to maintain concentrations of st below the relevant Occupational Exposure Limits, suitable respiratory protective equipment should be worn (see 『personal protection』 below).

Personal Protection:
All PPE, including RPE, used to control exposure to hazardous substances must be selected to meet the relevant requirements.

Respiratory Protection:
Suitable respiratory protective equipment should be worn when this proct is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and the engineering controls and methods cannot reasonably be improved.

Hand Protection:
Where skin exposure may occur, advice should be sought from glove suppliers on appropriate types.

Eye protection:
Eye protection designed to protect against exposure to sts should be worn when there is a likelihood of exposure.

Skin Protection:
Cotton or cotton/ synthetic overalls or overalls are normally suitable.
Care should be taken in the selection of protective clothing to ensure that inflammation and irritation of the skin at the neck and wrists through contact with the powder is avoided.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Fine powder
Specific Gravity: 1.2—1.9
Solubility in water: insoluble
Minimum ignition temp: 400℃
Minimum ignition energy: 5—20mJ
Minimum explosive concentration: 20—70g/m3

10. STABILITY AND REACTIVITY

Stable under the recommended storage and handling conditions (See Section 7). In a fire, hazardous decomposition procts such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be proced.

11. TOXICOLOGICAL INFORMATION

There is no data available on the proct itself. Coating powders can cause localized skin irritation in folds of the skin or in contact with tight clothing.

12. ECOLOGICAL INFORMATION

There is no data available on the proct itself.
This proct contains Triglycidyl Isocyanurate (TGIC) which is classified as harmful to aquatic organisms, and may cause long-term adverse effects in the aquatic environment.
The proct should not be allowed to enter drains or watercourses or be deposited where it can affect ground or surface waters.
The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this proct.

13. DISPOSAL CONSIDERATIONS

Do not allow into drains or watercourses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act.

14. TRANSPORT INFORMATION

Always transport in closed containers that are upright and secure. Ensure that persons transporting the proct know what to do in the event of accident or spillage.
The proct is not classified as dangerous for carriage under International regulations.

15. REGULATORY INFORMATION

The safety phrases of this proct is identified in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations (1997) as follows.

This proct contains Triglycidyl Isocyanurate (TGIC) and is classified as toxic.
R46 May cause heritable genetic damage
R43 May cause sensitisation by skin contact.
R36 Irritating to eyes.
R20/22 Harmful by inhalation and if swallowed
S24/25 Avoid contact with skin and eyes.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
S38 In case of insufficient ventilation wear suitable respiratory equipment.
S53 Avoid exposure –obtain special instructions before use.

The information contained in this safety data sheet does not constitute the user』s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc Act and the Control of Substances Hazardous to Health Regulations apply to the use of this proct at work.

16. OTHER INFORMATION

The information in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations 1997.

The full text of the R phrase contained in Section 2 is:-
R23/25 Toxic by inhalation and if swallowed.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R46 May cause heritable genetic damage.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.

The proct should not used for purposes other than those shown in Section 1 without first referring to the powder supplier and obtaining written handling instructions. As the specific conditions of use of the proct are outside the supplier』s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with.

The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the proct and should not be construed as any guarantee of technical performance or suitability for particular application.

Further information and relevant advice can be found in:
The Control of Substances Hazardous to Health Regulations 1999（SL1999：437）.
The Application of Powder Coatings by Electrostatic Spraying (Code of Safe Practice) from British Coatings Federation（01372 360 660）.
The Manual Handling Operations Regulations 1992（SL 1992：2793）.
Chemical Warehousing: Storage of Packaged Dangerous Substances HS（G）71
The Environmental Protection (Duty of Care) Regulations 1992（SL 1992：2839）.
The Chemicals (Hazard Information and Packaging) Regulations 1997（SL 1997：3247）.